Synthesis of (±)-trans-2,5-Diisopropylborolane
نویسندگان
چکیده
The cyclic hydroboration of 2,7-dimethyl-2,6-octadiene (6) was studied. It was found that the stereochemical outcome of the reaction was dependent upon the solvent, temperature, time and the nature of the borane reagent. Pure racemic trans-2,5diisopropylborolane (14) was isolated following selective complexation of the cis-2,5diisopropylborolane (15) with 1-(2-hydroxyethyl)-pyrrolidine.
منابع مشابه
Crystal Structure of Trans- [bis(2,5-dichlorophenylcyanamido) {N,N′-propanediylbis(2,3-butadien-2-imine-3-oxime)} Cobalt(III)], trans-[Co((DO)(DOH)pn)(2,5-Cl2pcyd)2]
The first crystal structure of a phenylcyanamide cobaltoxime (cobaloxime) complex is reported. This compound is trans-[Co((DO)(DOH)pn)(2,5-Cl2pcyd)2], and consits of an imine-oxime equatorial ligand ((DO)(DOH)pn) and two 2,5-dichlorophenylcyanamide ligands in axial positions. Crystals of trans- [Co((DO)(DOH)pn)(2,5-Cl2pcyd)2] were grown by ether diffusion into an acetonitrile solution of the co...
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